View Article |
Effect of crystallinity of zeolite beta on physicochemical properties and performance of cobalt catalysts
Piaw Phatai1, Sirinuch Loiha2, Sanchai Prayoonpokarach3, Jatuporn Wittayakun4.
In the present work, the effect of crystallinity of zeolite beta in a sodium form (NaBEA) on physicochemical properties and performance of NaBEA-supported cobalt catalysts was investigated. The incipient wetness impregnation method was utilized in the synthesis of NaBEA-supported cobalt catalysts with various Co loadings (4, 7 and 10 wt. %). NaBEA materials with high and low crystallinities (NaBEA-H and NaBEA-L) were synthesized using fumed silica with aging times of 72 and 48 h, respectively. In comparison to NaBEA-L, higher XRD peak intensities and surface area were observed for NaBEA-H. After impregnation, NaBEA-L displayed better dispersion of Co species and lower reducibility than NaBEA-H due to stronger metal-support interaction. Catalytic performance for n-butane hydrogenolysis via Co/ NaBEA-H and Co/NaBEA-L catalysts was compared. In butane hydrogenolysis, the higher conversion was attained using Co/NaBEA-H with 7 and 10 wt. % when compared to Co/NaBEA-L with similar loadings. Multiple hydrogenolysis occurred on all catalysts producing methane as the only product. The most effective catalyst was determined to be 7Co/ NaBEA-H due to the higher surface area and uniform particles of the cobalt species.
Affiliation:
- Udon Thani Rajabhat University, Thailand
- Khon Kaen University, Thailand
- Suranaree University of Technology, Thailand
- Suranaree University of Technology, Thailand
Toggle translation
|
|
Indexation |
Indexed by |
MyJurnal (2021) |
H-Index
|
6 |
Immediacy Index
|
0.000 |
Rank |
0 |
Indexed by |
Web of Science (SCIE - Science Citation Index Expanded) |
Impact Factor
|
JCR (1.009) |
Rank |
Q4 (Multidisciplinary Sciences) |
Additional Information |
JCI (0.15) |
Indexed by |
Scopus 2020 |
Impact Factor
|
CiteScore (1.4) |
Rank |
Q2 (Multidisciplinary) |
Additional Information |
SJR (0.251) |
|
|
|