Integrating the Internet of Things (IoT) and natural fiber-reinforced polymer composites (NFPCs) can revolutionize monitoring and maintaining composites. By incorporating sensors and wireless communication technology into the composites, real-time monitoring and predictive maintenance can be achieved. This review provides a comprehensive overview of the current state-of-the-art in the use of IoT for real-time monitoring and predictive maintenance of NFPCs. This paper covers the various types of sensors used, IoT networks and protocols employed, and data analysis techniques to detect potential issues and predict failures. This paper also highlights the benefits and challenges of using IoT for composite maintenance and this technology’s future directions and potential applications. This review provides valuable insights for researchers, engineers, and practitioners in composites, the IoT, and predictive maintenance.