Major drawbacks to high voltage insulator especially on electrical aging process have been an issue for decades. The internal electric field distribution due to the presence of local space charge will distort, which in turn may cause the insulating material to degrade and finally can lead to accelerated aging and electrical breakdown. Comprehension of space charge buildup in solid insulator is crucial to determine how aging occurs, thus enabling the prediction of insulator lifetime. Space charge measurement has been extensively researched in recent years and has become a common method of investigating solid insulator properties. Pressure Wave Propagation (PWP) and Pulsed Electro-Acoustic (PEA) are non-destructive dielectric testing methods used to determine the space charge distribution within the insulation. This paper presents the basic principles, typical measurement setup and comparison of results from several published papers on application of PWP and PEA methods to investigate space charge accumulation. The space charge distribution in the sample is measured as current and voltage signals obtained from PWP and PEA methods respectively. Judging from extracted results of other research, both methods show the capability to detect premature aging activities in the insulator, which is necessary for condition monitoring of high voltage insulators.