Precipitated calcium carbonate (PCC) chemically can be synthesized in the laboratory. In this study, hydrated lime or calcium hydroxide was used as raw material with sucrose as additive to produce PCC. The process was compared with the one without additive. PCC produced was observed based on morphology, mineral composition and size by using Fesem-Edx and LPSA, respectively. PCC products without additive demonstrated fine and more uniform size of calcite PCC as compared to the one with additive. Nevertheless, the process with additive produced more PCC product than without additive