River flow prediction is important in determining the amount of water in certain areas to ensure sufficient water resources to meet the demand. Hence, an analysis and prediction of multiple time-scales data for daily, weekly and 10-day averaged time series were performed using chaos approach. An analysis was conducted at the Tanjung Tualang station, Malaysia. This method involved the reconstruction of a single variable in a multi-dimensional phase space. River flow prediction was performed using local linear approximation. The prediction result is close to agreement with a high correlation coefficient for each time scale. The analysis suggests that the presence of low dimensional chaos as an optimal embedding dimension exists when the inverse method is adopted. In addition, a comparison of the prediction performance of chaos approach, autoregressive integrated moving average (ARIMA), artificial neural network (ANN), support vector machine (SVM) and least squares support vector machines (LSSVM) were performed. The comparative analysis shows that all methods provide comparable predictions. However, chaos approach provides a simpler means of analysis since it only use a scalar time series (river flow data). Therefore, the relevant authorities may use this prediction result for the creation of a water management system for local benefit.