View Article |
Model free kinetics analysis of imperata cylindrica (lalang)
Olagoke Oladokun1, Arshad Ahmad2, Tuan Amran Tuan Abdullah3, Bemgba Bevan Nyakuma4, Wong, Syie Luing5.
This study is the first attempt at investigating the solid state decomposition and the
devolatilization kinetics of Imperata cylindrica (lalang) grass termed the “farmer’s nightmare
weed” as a potential solid biofuel of the future. Biomass conversion technologies such as
pyrolysis and gasification can be utilized for future green energy needs. However an
important step in the efficient utilization and process optimizing of biomass conversion
processes is understanding the thermal decomposition kinetics of the feedstock.
Consequently, thermogravimetric analysis (TGA) of Imperata cylindrica was carried out in the
temperature range of 30-1000 °C at four heating rates of 5, 10, 15, and 20 K min-1 using
Nitrogen at a flow rate of 20 L min-1 as purge gas. Using the TGA results, the kinetic parameters
activation energy (Ea) and pre-exponential frequency factor (ko) of the grass were estimated
via the model free or isoconversional methods of Kissinger and Starink. The results obtained
for Kissinger model were 151.36 kJ moI-1 and 5.83 x 109 min-1 for activation energy and preexponential
frequency factor respectively. However, Starink model activation energy and
pre-exponential frequency factor were a function of conversion (α) with average values of
159.93 kJ mol-1 and 6.33 x 1022 min-1 respectively.
Affiliation:
- Universiti Teknologi Malaysia, Malaysia
- Universiti Teknologi Malaysia, Malaysia
- Universiti Teknologi Malaysia, Malaysia
- Universiti Teknologi Malaysia, Malaysia
- Universiti Teknologi Malaysia, Malaysia
Toggle translation
Download this article (This article has been downloaded 150 time(s))
|
|
Indexation |
Indexed by |
MyJurnal (2021) |
H-Index
|
6 |
Immediacy Index
|
0.000 |
Rank |
0 |
Indexed by |
Scopus 2020 |
Impact Factor
|
CiteScore (1.4) |
Rank |
Q3 (Engineering (all)) |
Additional Information |
SJR (0.191) |
|
|
|